A Highly‐Efficient Oxygen Evolution Electrocatalyst Derived from a Metal‐Organic Framework and Ketjenblack Carbon Material

نویسندگان

چکیده

The composite of the metal-organic framework (MOF) Ni(Fe)-MOF-74 and highly conductive carbon material ketjenblack (KB) could be easily obtained from in-situ MOF synthesis in a one-step solvothermal reaction. features remarkable electrochemical oxygen evolution reaction (OER) performance where overpotential at 10 mA/cm2 current density 1.7 VRHE are recorded as 0.274 650 mA/cm2, respectively, 1 mol/L KOH. In particular, activation nickel-iron clusters under an applied anodic bias steadily boosts OER performance. Although goes through some structural modification during measurements, stabilized optimized shows excellent This simple strategy to design highly-efficient electrocatalysts, utilizing readily available precursors materials, will leverage use diverse complexes into electrode fabrication with high energy conversion efficiency.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Nanoporous carbon derived from a functionalized metal-organic framework as a highly efficient oxygen reduction electrocatalyst.

High levels of iron-nitrogen doped porous carbon materials are obtained from MOF-253 using a step-by-step post-synthetic modification strategy. MOF-253 possessing open 2,2'-bipyridine nitrogen sites not only serves as a precursor but also provides chelate bonding sites for Fe2+. Followed by further impregnation of 1,10-phenanthroline, high surface area porous carbon materials are obtained. For ...

متن کامل

The Use of an Edible Mushroom-Derived Renewable Carbon Material as a Highly Stable Electrocatalyst towards Four-Electron Oxygen Reduction

The development of highly stable and efficient electrocatalysts for sluggish oxygen reduction reaction (ORR) is exceedingly significant for the commercialization of fuel cells but remains a challenge. We here synthesize a new nitrogen-doped biocarbon composite material (N-BC@CNP-900) as a nitrogen-containing carbon-based electrocatalyst for the ORR via facile all-solid-state multi-step pyrolysi...

متن کامل

Nickel Oxide/Carbon Nanotubes as Active Hybrid Material for Oxygen Evolution Reaction

Carbon nanotubes are of great interest due to their high surface area and rich edge sites, which are favorable for wide applications. Here, a simple and efficient routine is presented by decoration of multi-wall carbon nanotube (MWCNT) with nickel oxide (NiO) nanoparticles.The morphologies of NiO-MWCNT  were  investigated  by  using scanning  electron  microscope  (SEM)  and energydispersive X-...

متن کامل

A highly efficient electrocatalyst for the oxygen reduction reaction: N-doped ketjenblack incorporated into Fe/Fe3C-functionalized melamine foam.

Polarization caused by the oxygen reduction reaction (ORR) on cathodes still contributes significantly to the energy efficiency loss of metal–air batteries and fuel cells. Thus, ways of increasing the ORR kinetics while maintaining fast mass transfer is a grand challenge in the development of a new generation of metal–air batteries and fuel cells. Catalysts based on platinum and other precious ...

متن کامل

A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water

Oxygen reduction and water oxidation are two key processes in fuel cell applications. The oxidation of water to dioxygen is a 4 H+/4 e- process, while oxygen can be fully reduced to water by a 4 e-/4 H+ process or partially reduced by fewer electrons to reactive oxygen species such as H2O2 and O2-. We demonstrate that a novel manganese corrole complex behaves as a bifunctional catalyst for both...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Collection of Czechoslovak Chemical Communications

سال: 2021

ISSN: ['2192-6506']

DOI: https://doi.org/10.1002/cplu.202100278